Difference between revisions of "Iron filings (ZVI)"

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===How is it being used?===
 
===How is it being used?===
No projects that use ZVI were found in Ontario.  
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* A Maplewood,Minnesota field study developed an iron-enhanced (5% iron filings) ditch check sand filter for installation in [[Swales|swales]] to provide treatment of dissolved heavy metals and dissolved phosphorous in stormwater runoff from highways<ref>Farzana Ahmed, Poornima Natarajan, John S. Gulliver, Peter T. Weiss, John L. Nieber. 2014. Assessing and Improving Pollution Prevention by Swales. https://www.lrrb.org/pdf/201430.pdf</ref>.
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* No projects that use ZVI were found in Ontario.  
 
[[File:Screenshot 2025-08-13 113919.png|500px|thumb|[[Bioretention]] schematic, with circles highlighting ZVI addition and phosphorus removal <ref name = Lechner>Lechner L. Phosphorus Removal From Stormwater Using Zero-Valent Iron. 2016. Applied Science Masters Thesis.</ref>.]]
 
[[File:Screenshot 2025-08-13 113919.png|500px|thumb|[[Bioretention]] schematic, with circles highlighting ZVI addition and phosphorus removal <ref name = Lechner>Lechner L. Phosphorus Removal From Stormwater Using Zero-Valent Iron. 2016. Applied Science Masters Thesis.</ref>.]]
  

Revision as of 18:56, 13 August 2025

ZVI

What is it?[edit]

Iron filings or zero-valent iron (ZVI) is the elemental form of iron with a zero charge carried by each atom – a result of the outer valence level being filled. ZVI is able to remove dissolved phosphorus (phosphate) from solution through precipitation. [1] Zero-valent iron nanoparticles (nZVI) are also used for phosphorus removal.

How is it being used?[edit]

  • A Maplewood,Minnesota field study developed an iron-enhanced (5% iron filings) ditch check sand filter for installation in swales to provide treatment of dissolved heavy metals and dissolved phosphorous in stormwater runoff from highways[2].
  • No projects that use ZVI were found in Ontario.
Bioretention schematic, with circles highlighting ZVI addition and phosphorus removal [3].

Benefits[edit]

A study was done that compared the phosphorus reduction capabilities of ZVI, biochar, biochar-supported ZVI (ZVI/BC), and biochar-supported nZVI (nZVI/BC). [1] It was found that nZVI/BC had the highest phosphorus reduction. Using biochar-supported ZVI or nZVI improves the dispersion and stability of the iron filings. Biochar is fine-grained and highly porous, providing a large surface area to support nZVI. Another paper reports that ZVI can remove up to 98% of influent phosphorus at low input concentrations, and at high concentrations is shown to remove up to 36% of incoming phosphorus. The phosphorus retained in the soil is mostly iron-bound, which will not be easily leached out of the system because it is very stable.[3]

Back to additives.

  1. 1.0 1.1 Rossetti M. Evaluation of phosphorous removals by biochar supported nano-scale zero-valent iron. 2017. Chemical Engineering Undergraduate Honors Thesis.
  2. Farzana Ahmed, Poornima Natarajan, John S. Gulliver, Peter T. Weiss, John L. Nieber. 2014. Assessing and Improving Pollution Prevention by Swales. https://www.lrrb.org/pdf/201430.pdf
  3. 3.0 3.1 Lechner L. Phosphorus Removal From Stormwater Using Zero-Valent Iron. 2016. Applied Science Masters Thesis.